I'm sure that the results are on the board in terms of caffeine content being tried and tested numerous times, and an intrepid web surfer would be sure to find them Still, hats off to anyone who's willing or able to replicate these results through testing them themselves I still reckon though, and I don't have documented evidence to back me up - but common sense would seem to suggest that a 30ml pour from a single extraction is going to contain more caffeine than a 30ml pour from a double extraction Why? Because with the single the contents are under greater pressure, as there is only one outlet point, meaning a longer saturation time - which, to my mind at least means more caffeine When you extract the same amount of coffee from a double the extraction time is a lot less, which means that the water is in contact with the coffee for a lot less time, which to me suggests less caffeine extraction Certainly, the flavour profile of both pours is completely different, with the single extraction espresso exhibiting grater depth, complexity, and a more rounded mouth-feel, with, dare I say it, increased 'fleshiness' on the mid palate (depending upon the beans that you are using) Whereas the 'double ristretto' type extraction from the double basket produces a sweeter and some would say 'creamier' extraction, with 'bright' acidity and less bitterness I could be wrong here, but if that's the case I'd like to see the science to back up an alternative version of these events! Cheers, Pat