I reckon you're over thinking it a bit. Insulation = either insulating against heat loss or heat gain, in this case heat loss from anything copper. Therefore, to my way of thinking anyway, the boiler will retain heat better, transfer heat to the HX better, which makes the thermosyphon work better and makes the heat loss from the hx - group pipes less = a hotter or more stable shot. Reducing the energy loss at one point ( boiler, hx & lines) increases the potential energy at another point, in this case the group head. Now I'm over thinking it